New easily recycled carrier based polyurethane foam by loading Al-MOF and biochar for selective removal of fluoride ion from aqueous solutions.

The production of Integrated circuits (ICs) generates wastewater with a high concentration of residual fluoride ions, necessitating highly efficient fluorine removal methods. In this study, a novel composite carrier was developed using a hydrothermal synthesis method to load Al-MOF and biochar (BC) onto polyurethane foam (PUF), resulting in the composite foam of Al-MOF-PUF@BC. The results showed that the composite carrier exhibited a stable fluoride removal effect, with a maximum adsorption capacity of 16.52 mg/g at room temperature. The adsorption isotherm curves were consistent with the Langmuir isotherm model, and the adsorption kinetics were well-described by the pseudo-first-order model. The mechanism of fluorine adsorption on Al-MOF-PUF@BC was ligand exchange with hydroxyl groups and the formation of FAl bonds. Density functional theory (DFT) calculations revealed that the adsorption energy reached -246.7 eV, indicating stable adsorption for fluoride ions. The composite foam demonstrated excellent regenerative properties and was effective for fluoride removal in actual IC wastewater.

The adsorption of phosphate using a magnesia-pullulan composite: kinetics, equilibrium, and column tests.

A magnesia-pullulan (MgOP) composite has been developed to remove phosphate from a synthetic solution. In the present study, the removal of phosphate by MgOP was evaluated in both a batch and dynamic system. The batch experiments investigated the initial pH effect on the phosphate removal efficiency from pH 3 to 12 and the effect of co-existing anions. In addition, the adsorption isotherms, thermodynamics, and kinetics were also investigated. The results from the batch experiments indicate that MgOP has encouraging performance for the adsorption of phosphate, while the initial pH value (3-12) had a negligible influence on the phosphate removal efficiency. Analysis of the adsorption thermodynamics demonstrated that the phosphate removal process was endothermic and spontaneous. Investigations into the dynamics of the phosphate removal process were carried out using a fixed bed of MgOP, and the resulting breakthrough curves were used to describe the column phosphate adsorption process at various bed masses, volumetric flow rates, influent phosphate concentrations, reaction temperatures, and inlet pH values. The results suggest that the adsorption of phosphate on MgOP was improved using an increased bed mass, while the reaction temperature did not significantly affect the performance of the MgOP bed during the phosphate removal process. Furthermore, higher influent phosphate concentrations were beneficial towards increasing the column adsorption capacity for phosphate. Several mathematic models, including the Adams-Bohart, Wolboska, Yoon-Nelson, and Thomas models, were employed to fit the fixed-bed data. In addition, the effluent concentration of magnesium ions was measured and the regeneration of MgOP investigated.

Investigation of backwashing effectiveness in membrane bioreactor (MBR) based on different membrane fouling stages.

In this study the effect of different fouling stages of hollow fiber membranes on effective backwashing length in MBR has been investigated. Computational fluid dynamics (CFD) is imported to simulate backwashing process. A multi-physics coupling model for free porous media flow, convective mass transfer and diluted species transport was established. The laser bijection sensors (LBS) were imported to monitor the backwashing solution position inside fiber lumen. Simulation results indicated that membrane fouling degree could change the velocity of backwash solution inside fiber lumen and make a further effect on effective backwash length. The signal variations of LBS are in accordance with the simulation results. The backwashing process can only play an active role when the filtration pressure is below the critical TMP. It can be concluded that backwash duration in industrial applications need to be set based on changes in TMP.